You can do Capo 1 and change the E to F or no capo at all and play F#, it doesn't matter.

Capo 2

INTRO: E A E A E
E        A              E
Cocaine flame in my bloodstream
E                   A
Sold my coat when I hit Spokane
A
Bought myself a hard pack of cigarettes
                     E
In the early mornin' rain

E          A          E
Lately my hands they don't feel like mine
E                        A
My eyes been stung with dust and blind
A
Held you in my arms one time
                  E
Lost you just the same

CHORUS:
C#m  B    
Jolene
A                          E         A
Well, I ain't about to go straight, it's too late
E                   A                E
And I found myself face down in the ditch
B
Booze in my hair, blood on my lips
C#m
A picture of you holding a picture of me
A                      E
In the pocket of my blue jeans
C#m         B            A
Still don't know what love means
C#m         B                A   G#m F#m  B
Still don't know what love means

     E    A  E   A G#m F#m B
Jolene          La la la la
     E    A  E   A G#m F#m B
Jolene          La la la la

SOLO: Same thing as the intro (E A E A)

E            A                E
It's been so long since I've seen your face
E                A
Or felt a part of this human race
A
I've been living out of this here suitcase
E
For way too long
E             A             E
Man needs something he can hold onto
E                       A
Nine pound hammer or a woman like you
A                             E
Either one of them things will do

CHORUS:
C#m  B    
Jolene
A                          E         A
Well, I ain't about to go straight, it's too late
E                   A                E
And I found myself face down in the ditch
B
Booze in my hair, blood on my lips
C#m
A picture of you holding a picture of me
A                      E
In the pocket of my blue jeans
C#m         B            A
Still don't know what love means
C#m         B                A   G#m F#m  B
Still don't know what love means

     E    A  E   A G#m F#m B
Jolene          La la la la
     E    A  E   A G#m F#m B
Jolene          La la la la


E        A              E
Cocaine flame in my bloodstream
A
Sold my coat when I hit Spokane